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Place the frozen meatballs into the bottom of your slow cooker.
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In a medium mixing bowl, whisk together the BBQ sauce, brown sugar, soy sauce, vinegar, and the juice from the canned pineapple.
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Add the pineapple chunks and the chopped bell peppers to the slow cooker on top of the meatballs.
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Pour the sauce mixture over the ingredients and stir gently until everything is evenly coated.
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Cover the slow cooker and cook on Low for 3 to 4 hours, or on High for 1.5 to 2 hours, until the meatballs are heated through and the peppers are tender.
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Give the mixture a final stir before serving to ensure the glaze is well-distributed.
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Serve the meatballs and sauce over a bed of warm white rice and garnish with fresh sliced green onions.